A1 Journal article (refereed)
Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light (2021)


Shi, P., Tu, Y., Zhang, D., Wang, C., Truong, K., Rissanen, K., & Bolm, C. (2021). Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light. Advanced Synthesis and Catalysis, 363(10), 2552-2556. https://doi.org/10.1002/adsc.202100162


JYU authors or editors


Publication details

All authors or editors: Shi, Peng; Tu, Yongliang; Zhang, Duo; Wang, Chenyang; Truong, Khai‐Nghi; Rissanen, Kari; Bolm, Carsten

Journal or series: Advanced Synthesis and Catalysis

ISSN: 1615-4150

eISSN: 1615-4169

Publication year: 2021

Volume: 363

Issue number: 10

Pages range: 2552-2556

Publisher: Wiley

Publication country: Germany

Publication language: English

DOI: https://doi.org/10.1002/adsc.202100162

Publication open access: Openly available

Publication channel open access: Partially open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/74619


Abstract

By visible‐light photoredox catalysis with copper complexes, sulfoximidoyl chlorides add to terminal aryl alkynes to give the corresponding (E)‐β‐chlorovinyl sulfoximines with exclusive regio‐ and stereoselectivities in high yields. Two representative products have been characterized by X‐ray crystal structure analysis. Radicals appear to be decisive intermediates. As demonstrated by two subsequent reactions, the products can be derivatized.


Free keywords: alkyne addition; copper catalysis; difunctionalization; vinyl sulfoximine; visible-light photoredox catalysis


Contributing organizations


Ministry reporting: Yes

Reporting Year: 2021

Preliminary JUFO rating: 2


Last updated on 2021-09-08 at 13:47