A1 Journal article (refereed)
Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light (2021)


Shi, P., Tu, Y., Zhang, D., Wang, C., Truong, K., Rissanen, K., & Bolm, C. (2021). Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light. Advanced Synthesis and Catalysis, 363(10), 2552-2556. https://doi.org/10.1002/adsc.202100162


JYU authors or editors


Publication details

All authors or editorsShi, Peng; Tu, Yongliang; Zhang, Duo; Wang, Chenyang; Truong, Khai‐Nghi; Rissanen, Kari; Bolm, Carsten

Journal or seriesAdvanced Synthesis and Catalysis

ISSN1615-4150

eISSN1615-4169

Publication year2021

Publication date11/03/2021

Volume363

Issue number10

Pages range2552-2556

PublisherWiley

Publication countryGermany

Publication languageEnglish

DOIhttps://doi.org/10.1002/adsc.202100162

Publication open accessOpenly available

Publication channel open accessPartially open access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/74619


Abstract

By visible‐light photoredox catalysis with copper complexes, sulfoximidoyl chlorides add to terminal aryl alkynes to give the corresponding (E)‐β‐chlorovinyl sulfoximines with exclusive regio‐ and stereoselectivities in high yields. Two representative products have been characterized by X‐ray crystal structure analysis. Radicals appear to be decisive intermediates. As demonstrated by two subsequent reactions, the products can be derivatized.


Free keywordsalkyne addition; copper catalysis; difunctionalization; vinyl sulfoximine; visible-light photoredox catalysis


Contributing organizations


Ministry reportingYes

Reporting Year2021

JUFO rating2


Last updated on 2024-22-04 at 16:50