A1 Journal article (refereed)
Cation-translocation based isomerism offers a tool for the expansion of compressed helicates (2021)


Mevissen, C., Sommer, D., Vasanthakumar, S., Truong, K.-N., Rissanen, K., & Albrecht, M. (2021). Cation-translocation based isomerism offers a tool for the expansion of compressed helicates. Dalton Transactions, 50(27), 9372-9375. https://doi.org/10.1039/d1dt01707a


JYU authors or editors


Publication details

All authors or editors: Mevissen, Christian; Sommer, David; Vasanthakumar, Sabarina; Truong, Khai-Nghi; Rissanen, Kari; Albrecht, Markus

Journal or series: Dalton Transactions

ISSN: 1477-9226

eISSN: 1477-9234

Publication year: 2021

Volume: 50

Issue number: 27

Pages range: 9372-9375

Publisher: Royal Society of Chemistry (RSC)

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/d1dt01707a

Publication open access: Not open

Publication channel open access:


Abstract

A series of compressed M[Li313Ti2] (M = Li, Na, K, Rb, Cs) and expanded helicates M4[13Ti2] has been obtained. The helicates Li3[M13Ti2] or M4[13Ti2] with M = Na+, K+, Rb+, or Cs+ adopt the expanded structure in solution. By crystallization the compressed structures M[Li313Ti2] (M = Na, Rb) are obtained. This represents an example of cation-translocation based isomerism.


Keywords: chemistry; isomerism


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Ministry reporting: Yes

Preliminary JUFO rating: 1


Last updated on 2021-14-07 at 12:30