A1 Journal article (refereed)
Selective guest inclusion of linear C6 hydrocarbons in a Zn(ii) 1D coordination polymer (2021)

Caruso, M., Cametti, M., Rissanen, K., & Martí-Rujas, J. (2021). Selective guest inclusion of linear C6 hydrocarbons in a Zn(ii) 1D coordination polymer. New Journal of Chemistry, 45(28), 12448-12452. https://doi.org/10.1039/D1NJ02175C

JYU authors or editors

Publication details

All authors or editors: Caruso, Manfredi; Cametti, Massimo; Rissanen, Kari; Martí-Rujas, Javier

Journal or series: New Journal of Chemistry

ISSN: 1144-0546

eISSN: 1369-9261

Publication year: 2021

Volume: 45

Issue number: 28

Pages range: 12448-12452

Publisher: Royal Society of Chemistry (RSC)

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/D1NJ02175C

Publication open access: Not open

Publication channel open access:

Abstract

Trapping of volatile unbranched C6 hydrocarbons (hexane, 1-hexene, and 1-hexyne) in a 1D coordination polymer is reported. The guest inclusion was studied quantitatively by 1H-NMR analysis and thermogravimetric measurements, while synchrotron single-crystal diffraction data allowed advancing the view of their confinement into linear CP channels. Adsorption experiments performed through solid/vapour processes on microcrystals of CP 1 showed a certain degree of selectivity for 1-hexyne, which could be rationalized by its larger dipole moment.

Keywords: supramolecular chemistry; hydrocarbons; recovery (recapture); adsorption; polymers; organometallic compounds

Contributing organizations

Ministry reporting: Yes

Reporting Year: 2021

JUFO rating: 1